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1 Aniline
A colourless oily liquid obtained from coal tar by the reduction of nitrobenzene by means of iron and hydrochloric acid. It is the basis of many important dyes in the textile industries. Perhaps the most important colour is Aniline black, which is the fastest black known; it resists exposure to air and light and is quite fast to washing and soaping. -
2 Perkin, Sir William Henry
[br]b. 12 March 1838 London, Englandd. 14 July 1907 Sudbury, England[br]English chemist, discoverer of aniline dyes, the first synthetic dyestuffs.[br]He early showed an aptitude for chemistry and in 1853 entered the Royal College of Chemistry as a student under A.W.von Hofmann, the first Professor at the College. By the end of his first year, he had carried out his first piece of chemical research, on the action of cyanogen chloride on phenylamine, which he published in the Journal of the Chemical Society (1857). He became honorary assistant to von Hofmann in 1857; three years previously he had set up his own chemical laboratory at home, where he had discovered the first of the azo dyes, aminoazonapththalene. In 1856 Perkin began work on the synthesis of quinine by oxidizing a salt of allyl toluidine with potassium dichromate. Substituting aniline, he obtained a dark-coloured precipitate which proved to possess dyeing properties: Perkin had discovered the first aniline dye. Upon receiving favourable reports on the new material from manufacturers of dyestuffs, especially Pullars of Perth, Perkin resigned from the College and turned to the commercial exploitation of his discovery. This proved highly successful. From 1858, the dye was manufactured at his Greenford Green works as "Aniline Purple" or "Tyrian Purple". It was later to be referred to by the French as mauve. Perkin's discovery led to the development of the modern dyestuffs industry, supplanting dyes from the traditional vegetable sources. In 1869, he introduced two new methods for making the red dye alizarin, in place of the process that involved the use of the madder plant (Rubia tinctorum). In spite of German competition, he dominated the British market until the end of 1873. After eighteen years in chemical industry, Perkin retired and devoted himself entirely to the pure chemical research which he had been pursuing since the 1850s. He eventually contributed ninety papers to the Chemical Society and further papers to other bodies, including the Royal Society. For example, in 1867 he published his synthesis of unsaturated organic acids, known as "Perkin's synthesis". Other papers followed, on the structure of "Aniline Purple". In 1881 Perkin drew attention to the magnetic-rotatory power of some of the substances he had been dealing with. From then on, he devoted particular attention to the application of this phenomenon to the determination of chemical structure.Perkin won wide recognition for his discoveries and other contributions to chemistry.The half-centenary of his great discovery was celebrated in July 1906 and later that year he received a knighthood.[br]Principal Honours and DistinctionsKnighted 1906. FRS 1866. President, Chemical Society 1883–5. President, Society of Chemical Industry 1884–5. Royal Society Royal Medal 1879; Davy Medal 1889.Bibliography26 August 1856, British patent no. 1984 (Aniline Purple).1867, "The action of acetic anhydride upon the hydrides of salicyl, etc.", Journal of the Chemical Society 20:586 (the first description of Perkin's synthesis).Further ReadingS.M.Edelstein, 1961, biography in Great Chemists, ed. E.Farber, New York: Interscience, pp. 757–72 (a reliable, short account).R.Meldola, 1908, Journal of the Chemical Society 93:2,214–57 (the most detailed account).LRDBiographical history of technology > Perkin, Sir William Henry
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3 Coal Tar Colours
A large class of colouring matters obtained from aniline, naphthalene, phenol, and other distillates of coal tar. Also known as aniline dyes since aniline was the first to be discovered. -
4 Caro, Heinrich
[br]b. 13 February 1834 Poznan, Polandd. 11 October 1911 Dresden, Germany[br]German dyestuffi chemist.[br]Caro received vocational training as a dyer at the Gewerbeinstitut in Berlin from 1852, at the same time attending chemistry lectures at the university there. In 1855 he was hired as a colourist by a firm of calico printers in Mulheim an der Ruhr, where he was able to demonstrate the value of scientific training in solving practical problems. Two years later, the year after Perkin's discovery of aniline dyes, he was sent to England in order to learn the latest dyeing techniques. He took up a post an analytical chemist with the chemical firm Roberts, Dale \& Co. in Manchester; after finding a better way of synthesizing Perkin's mauve, he became a partner in the business. Caro was able to enlarge both his engineering experience and his chemical knowledge there, particularly by studying Hofmann's researches on the aniline dyes. He made several discoveries, including induline, Bismark brown and Martius yellow.Like other German chemists, however, he found greater opportunities opening up in Germany, and in 1866 he returned to take up a post in Bunsen's laboratory in Heidelberg. In 1868 Caro obtained the important directorship of Badische Anilin-Soda- Fabrik (BASF), the first true industrial research organization and leading centre of dyestuffs research. A steady stream of commercial successes followed. In 1869, after Graebe and Liebermann had showed him their laboratory synthesis of the red dye alizarin, Caro went on to develop a cheaper and commercially viable method. During the 1870s he collaborated with Adolf von Baeyer to make methylene blue and related dyes, and then went on to the azo dyes. His work on indigo was important, but was not crowned with commercial success; that came in 1897 when his successor at BASF discovered a suitable process for producing indigo on a commercial scale. Caro had resigned his post in 1889, by which time he had made notable contributions to German supremacy in the fast-developing dyestuffs industry.[br]Further ReadingA.Bernthsen, 1912, obituary, Berichte derDeutschen Chemischen Gesellschaft, 45; 1,987–2,042 (a substantial obituary).LRD -
5 Blueing
The tinting of yellowish wool or cotton, with aniline blue or other dye, to neutralise the yellow and give a neutral white appearance. -
6 Diazo Colours
A class of coal tar dyes obtained from aniline. -
7 Edison, Thomas Alva
SUBJECT AREA: Architecture and building, Automotive engineering, Electricity, Electronics and information technology, Metallurgy, Photography, film and optics, Public utilities, Recording, Telecommunications[br]b. 11 February 1847 Milan, Ohio, USAd. 18 October 1931 Glenmont[br]American inventor and pioneer electrical developer.[br]He was the son of Samuel Edison, who was in the timber business. His schooling was delayed due to scarlet fever until 1855, when he was 8½ years old, but he was an avid reader. By the age of 14 he had a job as a newsboy on the railway from Port Huron to Detroit, a distance of sixty-three miles (101 km). He worked a fourteen-hour day with a stopover of five hours, which he spent in the Detroit Free Library. He also sold sweets on the train and, later, fruit and vegetables, and was soon making a profit of $20 a week. He then started two stores in Port Huron and used a spare freight car as a laboratory. He added a hand-printing press to produce 400 copies weekly of The Grand Trunk Herald, most of which he compiled and edited himself. He set himself to learn telegraphy from the station agent at Mount Clements, whose son he had saved from being run over by a freight car.At the age of 16 he became a telegraphist at Port Huron. In 1863 he became railway telegraphist at the busy Stratford Junction of the Grand Trunk Railroad, arranging a clock with a notched wheel to give the hourly signal which was to prove that he was awake and at his post! He left hurriedly after failing to hold a train which was nearly involved in a head-on collision. He usually worked the night shift, allowing himself time for experiments during the day. His first invention was an arrangement of two Morse registers so that a high-speed input could be decoded at a slower speed. Moving from place to place he held many positions as a telegraphist. In Boston he invented an automatic vote recorder for Congress and patented it, but the idea was rejected. This was the first of a total of 1180 patents that he was to take out during his lifetime. After six years he resigned from the Western Union Company to devote all his time to invention, his next idea being an improved ticker-tape machine for stockbrokers. He developed a duplex telegraphy system, but this was turned down by the Western Union Company. He then moved to New York.Edison found accommodation in the battery room of Law's Gold Reporting Company, sleeping in the cellar, and there his repair of a broken transmitter marked him as someone of special talents. His superior soon resigned, and he was promoted with a salary of $300 a month. Western Union paid him $40,000 for the sole rights on future improvements on the duplex telegraph, and he moved to Ward Street, Newark, New Jersey, where he employed a gathering of specialist engineers. Within a year, he married one of his employees, Mary Stilwell, when she was only 16: a daughter, Marion, was born in 1872, and two sons, Thomas and William, in 1876 and 1879, respectively.He continued to work on the automatic telegraph, a device to send out messages faster than they could be tapped out by hand: that is, over fifty words per minute or so. An earlier machine by Alexander Bain worked at up to 400 words per minute, but was not good over long distances. Edison agreed to work on improving this feature of Bain's machine for the Automatic Telegraph Company (ATC) for $40,000. He improved it to a working speed of 500 words per minute and ran a test between Washington and New York. Hoping to sell their equipment to the Post Office in Britain, ATC sent Edison to England in 1873 to negotiate. A 500-word message was to be sent from Liverpool to London every half-hour for six hours, followed by tests on 2,200 miles (3,540 km) of cable at Greenwich. Only confused results were obtained due to induction in the cable, which lay coiled in a water tank. Edison returned to New York, where he worked on his quadruplex telegraph system, tests of which proved a success between New York and Albany in December 1874. Unfortunately, simultaneous negotiation with Western Union and ATC resulted in a lawsuit.Alexander Graham Bell was granted a patent for a telephone in March 1876 while Edison was still working on the same idea. His improvements allowed the device to operate over a distance of hundreds of miles instead of only a few miles. Tests were carried out over the 106 miles (170 km) between New York and Philadelphia. Edison applied for a patent on the carbon-button transmitter in April 1877, Western Union agreeing to pay him $6,000 a year for the seventeen-year duration of the patent. In these years he was also working on the development of the electric lamp and on a duplicating machine which would make up to 3,000 copies from a stencil. In 1876–7 he moved from Newark to Menlo Park, twenty-four miles (39 km) from New York on the Pennsylvania Railway, near Elizabeth. He had bought a house there around which he built the premises that would become his "inventions factory". It was there that he began the use of his 200- page pocket notebooks, each of which lasted him about two weeks, so prolific were his ideas. When he died he left 3,400 of them filled with notes and sketches.Late in 1877 he applied for a patent for a phonograph which was granted on 19 February 1878, and by the end of the year he had formed a company to manufacture this totally new product. At the time, Edison saw the device primarily as a business aid rather than for entertainment, rather as a dictating machine. In August 1878 he was granted a British patent. In July 1878 he tried to measure the heat from the solar corona at a solar eclipse viewed from Rawlins, Wyoming, but his "tasimeter" was too sensitive.Probably his greatest achievement was "The Subdivision of the Electric Light" or the "glow bulb". He tried many materials for the filament before settling on carbon. He gave a demonstration of electric light by lighting up Menlo Park and inviting the public. Edison was, of course, faced with the problem of inventing and producing all the ancillaries which go to make up the electrical system of generation and distribution-meters, fuses, insulation, switches, cabling—even generators had to be designed and built; everything was new. He started a number of manufacturing companies to produce the various components needed.In 1881 he built the world's largest generator, which weighed 27 tons, to light 1,200 lamps at the Paris Exhibition. It was later moved to England to be used in the world's first central power station with steam engine drive at Holborn Viaduct, London. In September 1882 he started up his Pearl Street Generating Station in New York, which led to a worldwide increase in the application of electric power, particularly for lighting. At the same time as these developments, he built a 1,300yd (1,190m) electric railway at Menlo Park.On 9 August 1884 his wife died of typhoid. Using his telegraphic skills, he proposed to 19-year-old Mina Miller in Morse code while in the company of others on a train. He married her in February 1885 before buying a new house and estate at West Orange, New Jersey, building a new laboratory not far away in the Orange Valley.Edison used direct current which was limited to around 250 volts. Alternating current was largely developed by George Westinghouse and Nicola Tesla, using transformers to step up the current to a higher voltage for long-distance transmission. The use of AC gradually overtook the Edison DC system.In autumn 1888 he patented a form of cinephotography, the kinetoscope, obtaining film-stock from George Eastman. In 1893 he set up the first film studio, which was pivoted so as to catch the sun, with a hinged roof which could be raised. In 1894 kinetoscope parlours with "peep shows" were starting up in cities all over America. Competition came from the Latham Brothers with a screen-projection machine, which Edison answered with his "Vitascope", shown in New York in 1896. This showed pictures with accompanying sound, but there was some difficulty with synchronization. Edison also experimented with captions at this early date.In 1880 he filed a patent for a magnetic ore separator, the first of nearly sixty. He bought up deposits of low-grade iron ore which had been developed in the north of New Jersey. The process was a commercial success until the discovery of iron-rich ore in Minnesota rendered it uneconomic and uncompetitive. In 1898 cement rock was discovered in New Village, west of West Orange. Edison bought the land and started cement manufacture, using kilns twice the normal length and using half as much fuel to heat them as the normal type of kiln. In 1893 he met Henry Ford, who was building his second car, at an Edison convention. This started him on the development of a battery for an electric car on which he made over 9,000 experiments. In 1903 he sold his patent for wireless telegraphy "for a song" to Guglielmo Marconi.In 1910 Edison designed a prefabricated concrete house. In December 1914 fire destroyed three-quarters of the West Orange plant, but it was at once rebuilt, and with the threat of war Edison started to set up his own plants for making all the chemicals that he had previously been buying from Europe, such as carbolic acid, phenol, benzol, aniline dyes, etc. He was appointed President of the Navy Consulting Board, for whom, he said, he made some forty-five inventions, "but they were pigeonholed, every one of them". Thus did Edison find that the Navy did not take kindly to civilian interference.In 1927 he started the Edison Botanic Research Company, founded with similar investment from Ford and Firestone with the object of finding a substitute for overseas-produced rubber. In the first year he tested no fewer than 3,327 possible plants, in the second year, over 1,400, eventually developing a variety of Golden Rod which grew to 14 ft (4.3 m) in height. However, all this effort and money was wasted, due to the discovery of synthetic rubber.In October 1929 he was present at Henry Ford's opening of his Dearborn Museum to celebrate the fiftieth anniversary of the incandescent lamp, including a replica of the Menlo Park laboratory. He was awarded the Congressional Gold Medal and was elected to the American Academy of Sciences. He died in 1931 at his home, Glenmont; throughout the USA, lights were dimmed temporarily on the day of his funeral.[br]Principal Honours and DistinctionsMember of the American Academy of Sciences. Congressional Gold Medal.Further ReadingM.Josephson, 1951, Edison, Eyre \& Spottiswode.R.W.Clark, 1977, Edison, the Man who Made the Future, Macdonald \& Jane.IMcN -
8 Hofmann, August Wilhelm von
SUBJECT AREA: Chemical technology[br]b. 8 April 1818 Giessen, Germanyd. 2 May 1892 Berlin, Germany[br]German organic chemist.[br]The son of an architect, Hofmann began studying law and languages but was increasingly drawn to chemistry, attracted by Liebig's teaching at Giessen. In 1841 Hofmann took his doctorate with a study of coal tar. He became Privatdozent at Bonn University in 1845, but later that year he was persuaded to take up the post of first Director of the Royal College of Chemistry in London, after tenure was guaranteed as a result of Prince Albert's influence. He remained there for twenty years until he was offered professorships in chemistry at Bonn and Berlin. He accepted the latter. Hofmann continued the method of teaching chemistry, based on laboratory instruction, developed by Liebig at Giessen, and extended it to England and Berlin. A steady stream of well-trained chemists issued forth from Hofmann's tuition, concerning themselves especially with experimental organic chemistry and the industrial applications of chemistry. In 1848 one of his students, C.B. Mansfield, devised the method of fractional distillation of coal tar, to separate pure benzene, xylene and toluene, thus laying the foundations of the coal-tar industry. In 1856 another student, W.H. Perkin, prepared the first synthetic dyestuff, aniline purple, heralding the great dyestuffs industry, in which several other of his students distinguished themselves. Although keenly interested in the chemistry of dyestuffs, Hofmann did not pursue their large-scale preparation, but he stressed the importance of scientific research for success on a commercial scale. Hofmann's stimulus in this direction flagged after his return to Germany, and this was a factor in the failure of British industry to follow up their initial advantage and allow it to pass to Germany. In 1862 Hofmann prepared a dye from a derivative of triphenylmethane, which he called rosaniline. From this he derived a series of beautiful colours, ranging from blue to violet, which he patented as "Hofmann's violets" the following year.[br]Principal Honours and DistinctionsEnnobled 1888.Further ReadingJ.Volhard and E.Fischer, 1902, August Wilhelm von Hofmann, ein Lebensbild, Berlin (the basic biography).K.M.Hammond, 1967, bibliography, unpublished, (Diploma in Librarianship, London University (lists 373 items; deposited in University College, London)).LRDBiographical history of technology > Hofmann, August Wilhelm von
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9 Joly, John
SUBJECT AREA: Photography, film and optics[br]b. 1857 Holywood, King's County (now County Down, Northwern Ireland), Irelandd. 8 December 1933 Dublin, Eire[br]Irish pioneer of additive screen-plate colour photography.[br]Professor of Physics at Trinity College, Dublin, Joly developed a concept first suggested by Ducos du Hauron, creating in 1893 a process in which fine transparent red, green and blue lines, less than 0.1 mm wide, were ruled on a glass plate. The coloured inks were aniline dyes mixed with gum. This screen plate was held in close contact with a photographic negative plate which was exposed through the screen in a camera. The processed negative was printed onto a positive plate, and a viewing screen, similar to that used for taking, was bound up with it in careful register, to reproduce the original colours. The process was patented in 1894, and marketed in 1895. It was the first commercially successful additive screen-plate process to appear. While the results could be quite acceptable, the inadequate colour sensitivity of the negative plates then available limited the usefulness of this process. Professor Joly's other achievements included geological research and the treatment of cancer by radium.[br]Further ReadingJ.S.Friedman, 1944, History of Colour Photography, Boston.B.Coe, 1978, Colour Photography: The First Hundred Years, London. G.Koshofer, 1981, Farbfotografie, Vol. I, Munich.BC
См. также в других словарях:
ANILINE — L’aniline est un composé organique renfermant une fonction amine primaire, c’est à dire un atome d’azote lié à un carbone et à deux hydrogènes; l’atome de carbone appartenant à un noyau benzénique, il s’agit d’une amine aromatique, la plus simple … Encyclopédie Universelle
Aniline — An i*line, a. Made from, or of the nature of, aniline. [1913 Webster] … The Collaborative International Dictionary of English
Aniline — An i*line (?; 277), n. [See {Anil}.] (Chem.) An organic base belonging to the phenylamines. It may be regarded as ammonia in which one hydrogen atom has been replaced by the radical phenyl. It is a colorless, oily liquid, originally obtained from … The Collaborative International Dictionary of English
aniline — (n.) chemical base used in making colorful dyes, 1843, coined 1841 by German chemist Carl Julius Fritzsche (1808 1871) and adopted by Hofmann, ultimately from Port. anil the indigo shrub, from Arabic an nil the indigo, assimilated from al nil,… … Etymology dictionary
aniline — ► NOUN ▪ an oily liquid found in coal tar, used in the manufacture of dyes, drugs, and plastics. ORIGIN from an Arabic word meaning indigo (from which it was originally obtained) … English terms dictionary
aniline — [an′ə lin, an′əlēn΄, an′əlīn΄] n. [Ger anilin: see ANIL & INE3] a colorless, poisonous, oily liquid, C6H5NH2, a derivative of benzene used in making dyes, resins, rubber additives, fungicides, herbicides, etc., and in organic synthesis … English World dictionary
Aniline — For other uses, see Aniline (disambiguation). Aniline … Wikipedia
Aniline — Cet article possède un paronyme, voir : Alanine. Aniline … Wikipédia en Français
aniline — /an l in, uyn /, n. 1. Also called aniline oil, aminobenzine, phenylamine. Chem. a colorless, oily, slightly water soluble liquid, C6H5NH2, usually derived from nitrobenzene by reduction: used chiefly in the synthesis of dyes and drugs. adj. 2.… … Universalium
Aniline — A chemical compound implicated, along with o toluidine, in the causation of bladder cancer. Aniline and o toluidine, both aromatic amines, are used in the manufacture of a variety of dyes, pharmaceuticals, pesticides, and chemicals employed in… … Medical dictionary
aniline — /ˈænələn / (say anuhluhn) noun 1. an aromatic amine, aminobenzene, C6H5NH2, used in the manufacture of plastics, resins, etc. –adjective 2. relating to or derived from aniline: aniline colours. {anil + ine2} …
