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  • 61 Caro, Heinrich

    [br]
    b. 13 February 1834 Poznan, Poland
    d. 11 October 1911 Dresden, Germany
    [br]
    German dyestuffi chemist.
    [br]
    Caro received vocational training as a dyer at the Gewerbeinstitut in Berlin from 1852, at the same time attending chemistry lectures at the university there. In 1855 he was hired as a colourist by a firm of calico printers in Mulheim an der Ruhr, where he was able to demonstrate the value of scientific training in solving practical problems. Two years later, the year after Perkin's discovery of aniline dyes, he was sent to England in order to learn the latest dyeing techniques. He took up a post an analytical chemist with the chemical firm Roberts, Dale \& Co. in Manchester; after finding a better way of synthesizing Perkin's mauve, he became a partner in the business. Caro was able to enlarge both his engineering experience and his chemical knowledge there, particularly by studying Hofmann's researches on the aniline dyes. He made several discoveries, including induline, Bismark brown and Martius yellow.
    Like other German chemists, however, he found greater opportunities opening up in Germany, and in 1866 he returned to take up a post in Bunsen's laboratory in Heidelberg. In 1868 Caro obtained the important directorship of Badische Anilin-Soda- Fabrik (BASF), the first true industrial research organization and leading centre of dyestuffs research. A steady stream of commercial successes followed. In 1869, after Graebe and Liebermann had showed him their laboratory synthesis of the red dye alizarin, Caro went on to develop a cheaper and commercially viable method. During the 1870s he collaborated with Adolf von Baeyer to make methylene blue and related dyes, and then went on to the azo dyes. His work on indigo was important, but was not crowned with commercial success; that came in 1897 when his successor at BASF discovered a suitable process for producing indigo on a commercial scale. Caro had resigned his post in 1889, by which time he had made notable contributions to German supremacy in the fast-developing dyestuffs industry.
    [br]
    Further Reading
    A.Bernthsen, 1912, obituary, Berichte derDeut
    schen Chemischen Gesellschaft, 45; 1,987–2,042 (a substantial obituary).
    LRD

    Biographical history of technology > Caro, Heinrich

  • 62 Coolidge, William David

    SUBJECT AREA: Electricity, Metallurgy
    [br]
    b. 23 October 1873 Hudson, Massachusetts, USA
    d. 3 February 1975 New York, USA
    [br]
    American physicist and metallurgist who invented a method of producing ductile tungsten wire for electric lamps.
    [br]
    Coolidge obtained his BS from the Massachusetts Institute of Technology (MIT) in 1896, and his PhD (physics) from the University of Leipzig in 1899. He was appointed Assistant Professor of Physics at MIT in 1904, and in 1905 he joined the staff of the General Electric Company's research laboratory at Schenectady. In 1905 Schenectady was trying to make tungsten-filament lamps to counter the competition of the tantalum-filament lamps then being produced by their German rival Siemens. The first tungsten lamps made by Just and Hanaman in Vienna in 1904 had been too fragile for general use. Coolidge and his life-long collaborator, Colin G. Fink, succeeded in 1910 by hot-working directly dense sintered tungsten compacts into wire. This success was the result of a flash of insight by Coolidge, who first perceived that fully recrystallized tungsten wire was always brittle and that only partially work-hardened wire retained a measure of ductility. This grasped, a process was developed which induced ductility into the wire by hot-working at temperatures below those required for full recrystallization, so that an elongated fibrous grain structure was progressively developed. Sintered tungsten ingots were swaged to bar at temperatures around 1,500°C and at the end of the process ductile tungsten filament wire was drawn through diamond dies around 550°C. This process allowed General Electric to dominate the world lamp market. Tungsten lamps consumed only one-third the energy of carbon lamps, and for the first time the cost of electric lighting was reduced to that of gas. Between 1911 and 1914, manufacturing licences for the General Electric patents had been granted for most of the developed work. The validity of the General Electric monopoly was bitterly contested, though in all the litigation that followed, Coolidge's fibering principle was upheld. Commercial arrangements between General Electric and European producers such as Siemens led to the name "Osram" being commonly applied to any lamp with a drawn tungsten filament. In 1910 Coolidge patented the use of thoria as a particular additive that greatly improved the high-temperature strength of tungsten filaments. From this development sprang the technique of "dispersion strengthening", still being widely used in the development of high-temperature alloys in the 1990s. In 1913 Coolidge introduced the first controllable hot-cathode X-ray tube, which had a tungsten target and operated in vacuo rather than in a gaseous atmosphere. With this equipment, medical radiography could for the first time be safely practised on a routine basis. During the First World War, Coolidge developed portable X-ray units for use in field hospitals, and between the First and Second World Wars he introduced between 1 and 2 million X-ray machines for cancer treatment and for industrial radiography. He became Director of the Schenectady laboratory in 1932, and from 1940 until 1944 he was Vice-President and Director of Research. After retirement he was retained as an X-ray consultant, and in this capacity he attended the Bikini atom bomb trials in 1946. Throughout the Second World War he was a member of the National Defence Research Committee.
    [br]
    Bibliography
    1965, "The development of ductile tungsten", Sorby Centennial Symposium on the History of Metallurgy, AIME Metallurgy Society Conference, Vol. 27, ed. Cyril Stanley Smith, Gordon and Breach, pp. 443–9.
    Further Reading
    D.J.Jones and A.Prince, 1985, "Tungsten and high density alloys", Journal of the Historical Metallurgy Society 19(1):72–84.
    ASD

    Biographical history of technology > Coolidge, William David

  • 63 Dallos, Joseph

    [br]
    b. 1906 Budapest, Hungary
    d. 27 June 1979 London, England
    [br]
    Hungarian ophthalmologist and contact-lens specialist who pioneered the technique of individually fitted moulded-glass contact lenses.
    [br]
    Dallos graduated from the University of Budapest in 1929 and almost at once specialized in contact-lens work and was appointed Assistant Professor. At that time the fitting of lenses was and had been, since their inception c.1885, a matter of trial and error. He developed a method of taking a moulding of the surface of the eye and then producing a blown-glass lens to this shape. His work was based on a concept of corneal physiology and the need to maintain its normal respiration and metabolism.
    In 1937 he was invited to England to set up a centre in London making these innovations available. During the Second World War he worked in collaboration with the services and their special needs, and at its conclusion was invited to work at Moorfields Eye Hospital and later at the Western Opthalmic Hospital. Although plastic materials have now superseded Dallos's technology, the fundamental basis of his work remains relevant.
    [br]
    Bibliography
    1933, "Über Haftgläser und Kontaktschalen", Klin. med. Augenheilk. 1937, "The individual fitting of contact lenses", Trans. Ophth. Soc. UK. 1930–37, Papers in the Klinische Monatsblätter fur Augenheilkunde.
    Further Reading
    S.Duke-Elder, 1970, System of Ophthalmology, Vol. 5, London.
    MG

    Biographical history of technology > Dallos, Joseph

  • 64 Deville, Henri Etienne Sainte-Claire

    SUBJECT AREA: Metallurgy
    [br]
    b. 11 March 1818 St Thomas, Virgin Islands
    d. 1 July 1881 Boulogne-sur-Seine, France
    [br]
    French chemist and metallurgist, pioneer in the large-scale production of aluminium and other light metals.
    [br]
    Deville was the son of a prosperous shipowner with diplomatic duties in the Virgin Islands. With his elder brother Charles, who later became a distinguished physicist, he was sent to Paris to be educated. He took his degree in medicine in 1843, but before that he had shown an interest in chemistry, due particularly to the lectures of Thenard. Two years later, with Thenard's influence, he was appointed Professor of Chemistry at Besançon. In 1851 he was able to return to Paris as Professor at the Ecole Normale Supérieure. He remained there for the rest of his working life, greatly improving the standard of teaching, and his laboratory became one of the great research centres of Europe. His first chemical work had been in organic chemistry, but he then turned to inorganic chemistry, specifically to improve methods of producing the new and little-known metal aluminium. Essentially, the process consisted of forming sodium aluminium trichloride and reducing it with sodium to metallic aluminium. He obtained sodium in sufficient quantity by reducing sodium carbonate with carbon. In 1855 he exhibited specimens of the metal at the Paris Exhibition, and the same year Napoleon III asked to see them, with a view to using it for breastplates for the Army and for spoons and forks for State banquets. With the resulting government support, he set up a pilot plant at Jarvel to develop the process, and then set up a small company, the Société d'Aluminium at Nan terre. This raised the output of this attractive and useful metal, so it could be used more widely than for the jewellery to which it had hitherto been restricted. Large-scale applications, however, had to await the electrolytic process that began to supersede Deville's in the 1890s. Deville extended his sodium reduction method to produce silicon, boron and the light metals magnesium and titanium. His investigations into the metallurgy of platinum revolutionized the industry and led in 1872 to his being asked to make the platinum-iridium (90–10) alloy for the standard kilogram and metre. Deville later carried out important work in high-temperature chemistry. He grieved much at the death of his brother Charles in 1876, and his retirement was forced by declining health in 1880; he did not survive for long.
    [br]
    Bibliography
    Deville published influential books on aluminium and platinum; these and all his publications are listed in the bibliography in the standard biography by J.Gray, 1889, Henri Sainte-Claire Deville: sa vie et ses travaux, Paris.
    Further Reading
    M.Daumas, 1949, "Henri Sainte-Claire Deville et les débuts de l'industrie de l'aluminium", Rev.Hist.Sci 2:352–7.
    J.C.Chaston, 1981, "Henri Sainte-Claire Deville: his outstanding contributions to the chemistry of the platinum metals", Platinum Metals Review 25:121–8.
    LRD

    Biographical history of technology > Deville, Henri Etienne Sainte-Claire

  • 65 Mond, Ludwig

    SUBJECT AREA: Chemical technology
    [br]
    b. 7 March 1839 Cassel, Germany
    d. 11 December 1909 London, England
    [br]
    German (naturalized English) industrial chemist.
    [br]
    Born into a prosperous Jewish merchant family, Mond studied at the Polytechnic in Cassel and then under the distinguished chemists Hermann Kolbe at Marburg and Bunsen at Heidelberg from 1856. In 1859 he began work as an industrial chemist in various works in Germany and Holland. At this time, Mond was pursuing his method for recovering sulphur from the alkali wastes in the Leblanc soda-making process. Mond came to England in 1862 and five years later settled permanently, in partnership with John Hutchinson \& Co. at Widnes, to perfect his process, although complete success eluded him. He became a naturalized British subject in 1880.
    In 1872 Mond became acquainted with Ernest Solvay, the Belgian chemist who developed the ammonia-soda process which finally supplanted the Leblanc process. Mond negotiated the English patent rights and set up the first ammoniasoda plant in England at Winnington in Cheshire, in partnership with John Brunner. After overcoming many difficulties by incessant hard work, the process became a financial success and in 1881 Brunner, Mond \& Co. was formed, for a time the largest alkali works in the world. In 1926 the company merged with others to form Imperial Chemical Industries Ltd (ICI). The firm was one of the first to adopt the eight-hour day and to provide model dwellings and playing fields for its employees.
    From 1879 Mond took up the production of ammonia and this led to the Mond producer-gas plant, patented in 1883. The process consisted of passing air and steam over coal and coke at a carefully regulated temperature. Ammonia was generated and, at the same time, so was a cheap and useful producer gas. Mond's major discovery followed the observation in 1889 that carbon monoxide could combine with nickel in its ore at around 60°C to form a gaseous compound, nickel carbonyl. This, on heating to a higher temperature, would then decompose to give pure nickel. Mond followed up this unusual way of producing and purifying a metal and by 1892 had succeeded in setting up a pilot plant to perfect a large-scale process and went on to form the Mond Nickel Company.
    Apart from being a successful industrialist, Mond was prominent in scientific circles and played a leading role in the setting up of the Society of Chemical Industry in 1881. The success of his operations earned him great wealth, much of which he donated for learned and charitable purposes. He formed a notable collection of pictures which he bequeathed to the National Gallery.
    [br]
    Principal Honours and Distinctions
    FRS 1891.
    Bibliography
    1885, "On the origin of the ammonia-soda process", Journal of the Society of Chemical Industry 4:527–9.
    1895. "The history of the process of nickel extraction", Journal of the Society of Chemical Industry 14:945–6.
    Further Reading
    J.M.Cohen, 1956, The Life of Ludwig Mond, London: Methuen. Obituary, 1918, Journal of the Chemical Society 113:318–34.
    F.C.Donnan, 1939, Ludwig Mond 1839–1909, London (a valuable lecture).
    LRD

    Biographical history of technology > Mond, Ludwig

  • 66 Pierce, John Robinson

    [br]
    b. 27 March 1910 Des Moines, Iowa, USA
    [br]
    American scientist and communications engineer said to be the "father" of communication satellites.
    [br]
    From his high-school days, Pierce showed an interest in science and in science fiction, writing under the pseudonym of J.J.Coupling. After gaining Bachelor's, Master's and PhD degrees at the California Institute of Technology (CalTech) in Pasadena in 1933, 1934 and 1936, respectively, Pierce joined the Bell Telephone Laboratories in New York City in 1936. There he worked on improvements to the travelling-wave tube, in which the passage of a beam of electrons through a helical transmission line at around 7 per cent of the speed of light was made to provide amplification at 860 MHz. He also devised a new form of electrostatically focused electron-multiplier which formed the basis of a sensitive detector of radiation. However, his main contribution to electronics at this time was the invention of the Pierce electron gun—a method of producing a high-density electron beam. In the Second World War he worked with McNally and Shepherd on the development of a low-voltage reflex klystron oscillator that was applied to military radar equipment.
    In 1952 he became Director of Electronic Research at the Bell Laboratories' establishment, Murray Hill, New Jersey. Within two years he had begun work on the possibility of round-the-world relay of signals by means of communication satellites, an idea anticipated in his early science-fiction writings (and by Arthur C. Clarke in 1945), and in 1955 he published a paper in which he examined various possibilities for communications satellites, including passive and active satellites in synchronous and non-synchronous orbits. In 1960 he used the National Aeronautics and Space Administration 30 m (98 1/2 ft) diameter, aluminium-coated Echo 1 balloon satellite to reflect telephone signals back to earth. The success of this led to the launching in 1962 of the first active relay satellite (Telstar), which weighed 170 lb (77 kg) and contained solar-powered rechargeable batteries, 1,000 transistors and a travelling-wave tube capable of amplifying the signal 10,000 times. With a maximum orbital height of 3,500 miles (5,600 km), this enabled a variety of signals, including full bandwidth television, to be relayed from the USA to large receiving dishes in Europe.
    From 1971 until his "retirement" in 1979, Pierce was Professor of Electrical Engineering at CalTech, after which he became Chief Technologist at the Jet Propulsion Laboratories, also in Pasadena, and Emeritus Professor of Engineering at Stanford University.
    [br]
    Principal Honours and Distinctions
    Institute of Electrical and Electronics Engineers Morris N.Liebmann Memorial Award 1947; Edison Medal 1963; Medal of Honour 1975. Franklin Institute Stuart Ballantine Award 1960. National Medal of Science 1963. Danish Academy of Science Valdemar Poulsen Medal 1963. Marconi Award 1974. National Academy of Engineering Founders Award 1977. Japan Prize 1985. Arthur C.Clarke Award 1987. Honorary DEng Newark College of Engineering 1961. Honorary DSc Northwest University 1961, Yale 1963, Brooklyn Polytechnic Institute 1963. Editor, Proceedings of the Institute of Radio Engineers 1954–5.
    Bibliography
    23 October 1956, US patent no. 2,768,328 (his development of the travelling-wave tube, filed on 5 November 1946).
    1947, with L.M.Field, "Travelling wave tubes", Proceedings of the Institute of Radio
    Engineers 35:108 (describes the pioneering improvements to the travelling-wave tube). 1947, "Theory of the beam-type travelling wave tube", Proceedings of the Institution of
    Radio Engineers 35:111. 1950, Travelling Wave Tubes.
    1956, Electronic Waves and Messages. 1962, Symbols, Signals and Noise.
    1981, An Introduction to Information Theory: Symbols, Signals and Noise: Dover Publications.
    1990, with M.A.Knoll, Signals: Revolution in Electronic Communication: W.H.Freeman.
    KF

    Biographical history of technology > Pierce, John Robinson

  • 67 Roebuck, John

    SUBJECT AREA: Chemical technology
    [br]
    b. 1718 Sheffield, England
    d. 17 July 1794
    [br]
    English chemist and manufacturer, inventor of the lead-chamber process for sulphuric acid.
    [br]
    The son of a prosperous Sheffield manufacturer, Roebuck forsook the family business to pursue studies in medicine at Edinburgh University. There he met Dr Joseph Black (1727–99), celebrated Professor of Chemistry, who aroused in Roebuck a lasting interest in chemistry. Roebuck continued his studies at Leyden, where he took his medical degree in 1742. He set up in practice in Birmingham, but in his spare time he continued chemical experiments that might help local industries.
    Among his early achievements was his new method of refining gold and silver. Success led to the setting up of a large laboratory and a reputation as a chemical consultant. It was at this time that Roebuck devised an improved way of making sulphuric acid. This vital substance was then made by burning sulphur and nitre (potassium nitrate) over water in a glass globe. The scale of the process was limited by the fragility of the glass. Roebuck substituted "lead chambers", or vessels consisting of sheets of lead, a metal both cheap and resistant to acids, set in wooden frames. After the first plant was set up in 1746, productivity rose and the price of sulphuric acid fell sharply. Success encouraged Roebuck to establish a second, larger plant at Prestonpans, near Edinburgh. He preferred to rely on secrecy rather than patents to preserve his monopoly, but a departing employee took the secret with him and the process spread rapidly in England and on the European continent. It remained the standard process until it was superseded by the contact process towards the end of the nineteenth century. Roebuck next turned his attention to ironmaking and finally selected a site on the Carron river, near Falkirk in Scotland, where the raw materials and water power and transport lay close at hand. The Carron ironworks began producing iron in 1760 and became one of the great names in the history of ironmaking. Roebuck was an early proponent of the smelting of iron with coke, pioneered by Abraham Darby at Coalbrookdale. To supply the stronger blast required, Roebuck consulted John Smeaton, who c. 1760 installed the first blowing cylinders of any size.
    All had so far gone well for Roebuck, but he now leased coal-mines and salt-works from the Duke of Hamilton's lands at Borrowstonness in Linlithgow. The coal workings were plagued with flooding which the existing Newcomen engines were unable to overcome. Through his friendship with Joseph Black, patron of James Watt, Roebuck persuaded Watt to join him to apply his improved steam-engine to the flooded mine. He took over Black's loan to Watt of £1,200, helped him to obtain the first steam-engine patent of 1769 and took a two-thirds interest in the project. However, the new engine was not yet equal to the task and the debts mounted. To satisfy his creditors, Roebuck had to dispose of his capital in his various ventures. One creditor was Matthew Boulton, who accepted Roebuck's two-thirds share in Watt's steam-engine, rather than claim payment from his depleted estate, thus initiating a famous partnership. Roebuck was retained to manage Borrowstonness and allowed an annuity for his continued support until his death in 1794.
    [br]
    Further Reading
    Memoir of John Roebuck in J.Roy. Soc. Edin., vol. 4 (1798), pp. 65–87.
    S.Gregory, 1987, "John Roebuck, 18th century entrepreneur", Chem. Engr. 443:28–31.
    LRD

    Biographical history of technology > Roebuck, John

  • 68 Turner, Richard

    [br]
    b. 1798 probably Dublin, Ireland d. 1881
    [br]
    Irish engineer offerrovitreous structures such as glasshouses and roofs of railway terminus buildings. Lime Street Station, Liverpool, erected 1849–50, was a notable example of the latter.
    [br]
    Turner's first glasshouse commission was for the Palm House at the Botanic Gardens in Belfast, begun in 1839; this structure was designed by Charles Lanyon, Turner being responsible for the ironwork construction. The Belfast Palm House was followed in 1843 by the Palm House for the Royal Dublin Society, but the structure for which Turner is best known is the famous Palm House in the Royal Botanic Gardens at Kew Gardens in London. This was originally designed in 1844 by the architect Decimus Burton, but his concept was rejected and Turner was asked to design a new one. Burton tried again, basing his new design upon that of Turner but also incorporating features that made it more similar to the famous Great Conservatory by Paxton at Chatsworth. Finally, Turner was contracted to build the Palm Stove in collaboration with Burton. Completed in 1848, the Kew Palm House is the finest example of the glasshouses of that era. This remarkable structure is simple but impressive: it is 362 ft (110 m) long and is covered by 45,000 ft2 (4,180 m2) of greenish glass. Inside, in the central taller part, a decorative, cast-iron, spiral staircase gives access to an upper gallery, from where tall plants may be clearly viewed; the roof rises to 62 ft (19 m). The curving, glazed panels, set in ribs of wrought iron, rise from a low masonry wall. The ingenious method of construction of these ribs was patented by Turner in 1846. It consists of wrought-iron tie rods inserted into hollow cast-iron tubes; these can be tightened after the erection of the building is complete, so producing a stable, balanced structure not unlike the concept of a timber-trussed roof. The Palm Stove has only recently undergone extensive adaptation to modern needs.
    [br]
    Further Reading
    J.Hix, 1974, The Glass House, Cambridge, Mass.: MIT Press, pp. 122–7 (the Palm House at Kew).
    U.Kulturmann, 1979, Architecture and Urbanism, Tokyo, pp. 76–81 (the Palm House at Kew).
    DY

    Biographical history of technology > Turner, Richard

  • 69 Dialectic

        Dialectic As in dialogue (Socrates) or debate over opposites (Hegel) and clash of material forces (Marx) producing dynamic change.
       Or, a process of reasoning based upon the analysis of opposing propositions. Socrates used the dialectic method of teaching by distinguishing between opinion and knowledge. Hegel and Marx developed dialectic conceptions of history in which for Hegel, opposing ideas were the key, while for Marx history was explained as the conflict of material forces. (Stumpf, 1994, p. 936)

    Historical dictionary of quotations in cognitive science > Dialectic

  • 70 denitrification of waste gas

    1. денитрификация газовых отходов

     

    денитрификация газовых отходов

    [ http://www.eionet.europa.eu/gemet/alphabetic?langcode=en]

    EN

    denitrification of waste gas
    Current methods for controlling NOx emissions in motor vehicles include retardation of spark timing, increasing the air/fuel ratio, injecting water into the cylinders, decreasing the compression ratio, and recirculating exhaust gas. For stationary sources, one abatement method is to use a lower NOx producing fuel or to modify the combustion process by injecting steam into the combustion chamber. (Source: PZ)
    [http://www.eionet.europa.eu/gemet/alphabetic?langcode=en]

    Тематики

    EN

    DE

    FR

    Англо-русский словарь нормативно-технической терминологии > denitrification of waste gas

  • 71 production logging technique

    Англо-русский словарь нормативно-технической терминологии > production logging technique

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