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Buchwald-Hartwig reaction — The Buchwald Hartwig reaction in its original scope is an organic reaction describing a coupling reaction between an aryl halide and an amine in presence of base and a palladium catalyst forming a new carbon nitrogen bond.:The X in the aryl… … Wikipedia
Migratory insertion — A migratory insertion is a type of reaction in organometallic chemistry wherein two ligands on a metal complex combine. It is a subset of reactions that very closely resembles the insertion reactions, and both are differentiated by the mechanism… … Wikipedia