applied+chemistry

SUBJECT AREA: Electricity

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Crookes entered the Royal College of Chemistry at the age of 15, and from 1850 to 1854 held the appointment of Assistant at the college. In 1854 he became Superintendent of the Meteorological Department at the Radcliffe Observatory in Oxford. He moved to a post at the College of Science in Chester the following year. Soon after this he inherited a large fortune and set up his own private laboratory in London. There he studied the nature of electrical discharges in gases at low pressure and discovered the dark space (later named after him) that surrounds the negative electrode, or cathode. He also established that the rays produced in the process (subsequently shown by J.J.Thompson to be a stream of electrons) not only travelled in straight lines, but were also capable of producing heat and/or light upon impact with suitable anode materials. Using a variety of new methods to investigate these "cathode" rays, he applied them to the spectral analysis of compounds of selenium and, as a result, in 1861 he discovered the element thallium, finally establishing its atomic weight in 1873. Following his discovery of thallium, he became involved in two main lines of research: the properties of rarified gases, and the investigation of the elements of the "rare earths". It was also during these experiments that he discovered the principle of the Crookes radiometer, a device in which light is converted into rotational motion and which used to be found frequently in the shop windows of English opticians. Also among the fruits of this work were the Crookes tubes and the development of spectacle lenses with differential ranges of radiational absorption. In the 1870s he became interested in spiritualism and acquired a reputation for his studies of psychic phenomena, but at the turn of the century he returned to traditional scientific investigations. In 1892 he wrote about the possibility of wireless telegraphy. His work in the field of radioactivity led to the invention of the spinthariscope, an early type of detector of alpha particles. In 1900 he undertook investigations into uranium which led to the study of scintillation, an important tool in the study of radioactivity.

While the theoretical basis of his work has not stood the test of time, his material discoveries, observations and investigations of new facts formed a basis on which others such as J.J. Thomson were to develop subatomic theory. His later involvement in the investigation of spiritualism led to much criticism, but could be justified on the basis of a belief in the duty to investigate all phenomena.

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KF / MG

SUBJECT AREA: Automotive engineering, Land transport, Mining and extraction technology, Steam and internal combustion engines

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Educated at Truro Grammar School, he then studied under Dr Avery at Wadebridge to become a doctor of medicine. He settled as a surgeon in Wadebridge, spending his leisure time in building an organ and in the study of chemistry and mechanical science. He married Elizabeth Symons in 1814, and in 1820 moved with his wife to London. He delivered a course of lectures at the Surrey Institution on the elements of chemical science, attended by, amongst others, the young Michael Faraday. While there, Gurney made his first invention, the oxyhydrogen blowpipe. For this he received the Gold Medal of the Society of Arts. He experimented with lime and magnesia for the production of an illuminant for lighthouses with some success. He invented a musical instrument of glasses played like a piano.

In 1823 he started experiments related to steam and locomotion which necessitated taking a partner in to his medical practice, from which he resigned shortly after. His objective was to produce a steam-driven vehicle to run on common roads. His invention of the steam-jet of blast greatly improved the performance of the steam engine. In 1827 he took his steam carriage to Cyfarthfa at the request of Mr Crawshaw, and while there applied his steam-jet to the blast furnaces, greatly improving their performance in the manufacture of iron. Much of the success of George Stephenson's steam engine, the Rocket was due to Gurney's steam blast.

In July 1829 Gurney made a historic trip with his road locomotive. This was from London to Bath and back, which was accomplished at a speed of 18 mph (29 km/h) and was made at the instigation of the Quartermaster-General of the Army. So successful was the carriage that Sir Charles Dance started to run a regular service with it between Gloucester and Cheltenham. This ran for three months without accident, until Parliament introduced prohibitive taxation on all self-propelled vehicles. A House of Commons committee proposed that these should be abolished as inhibiting progress, but this was not done. Sir Goldsworthy petitioned Parliament on the harm being done to him, but nothing was done and the coming of the railways put the matter beyond consideration. He devoted his time to finding other uses for the steam-jet: it was used for extinguishing fires in coal-mines, some of which had been burning for many years; he developed a stove for the production of gas from oil and other fatty substances, intended for lighthouses; he was responsible for the heating and the lighting of both the old and the new Houses of Parliament. His evidence after a colliery explosion resulted in an Act of Parliament requiring all mines to have two shafts. He was knighted in 1863, the same year that he suffered a stroke which incapacitated him. He retired to his house at Reeds, near Bude, where he was looked after by his daughter, Anna.

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SUBJECT AREA: Metallurgy

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Hadfield's father, Robert, set up a steelworks in Sheffield in 1872, one of the earliest to specialize in steel castings. After his education in Sheffield, during which he showed an interest in chemistry, Hadfield entered his father's works. His first act was to set up a laboratory, where he began systematically experimenting with alloy steels in order to improve the quality of the products of the family firm. In 1883 Hadfield found that by increasing the manganese content to 12.5 per cent, with a carbon content of 1.4 per cent, the resulting alloy showed extraordinary resistance to abrasive wear even though it was quite soft. It was soon applied in railway points and crossings, crushing and grinding machinery, and wherever great resistance to wear is required. Its lack of brittleness led to its use in steel helmets during the First World War. Hadfield's manganese steel was also non-magnetic, which was later of importance in the electrical industry. Hadfield's other great invention was that of silicon steel. Again after careful and systematic laboratory work, Hadfield found that a steel containing 3–4 per cent silicon and as little as possible of other elements was highly magnetic, which was to prove important in the electrical industry (e.g. reducing the weight and bulk of electrical transformers). Hadfield took over the firm on the death of his father in 1888, but he continued to lay great stress on the need for laboratory research to improve the quality and range of products. The steel-casting side of the business led to a flourishing armaments industry, and this, together with their expertise in alloy steels, made Hadfield's one of the great names in Sheffield and British steel until, sadly, it succumbed along with so many other illustrious names during the British economic recession of 1983. Hadfield had a keen interest in metallurgical history, particularly in his characteristically thorough examination of the alloys of iron prepared by Faraday at the Royal Institution. Hadfield was an enlightened employer and was one of the first to introduce the eight-hour day.

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SUBJECT AREA: Automotive engineering, Land transport, Metallurgy

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From his early years, Haynes was a practising Presbyterian and an active prohibitionist. He graduated in 1881 at Worcester, Massachusetts, and a spell of teaching in his home town was interrupted in 1884–5 while he attended the Johns Hopkins University in Baltimore. In 1886 he became permanently diverted by the discovery of natural gas in Portland. He was soon appointed Superintendent of the local gas undertaking, and then in 1890 he was hired by the Indiana Natural Gas \& Oil Company. While continuing his gas-company employment until 1901, Haynes conducted numerous metallurgical experiments. He also designed an automobile: this led to the establishment of the Haynes- Apperson Company at Kokomo as one of the earliest motor-car makers in North America. From 1905 the firm traded as the Haynes Automobile Company, and before its bankruptcy in 1924 it produced more than 50,000 cars. After 1905, Haynes found the first "Stellite" alloys of cobalt and chromium, and in 1910 he was publicizing the patented material. He then discovered the valuable hardening effect of tungsten, and in 1912 began applying the "improved" Stellite to cutting tools. Three years later, the Haynes Stellite Company was incorporated, with Haynes as President, to work the patents. It was largely from this source that Haynes became a millionaire in 1920. In April 1912, Haynes's attempt to patent the use of chromium with iron to render the product rustless was unsuccessful. However, he re-applied for a US patent on 12 March 1915 and, although this was initially rejected, he persevered and finally obtained recognition of his modified claim. The American Stainless Steel Company licensed the patents of Brearley and Haynes jointly in the USA until the 1930s.

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SUBJECT AREA: Chemical technology

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Orphaned at an early age, Leblanc was sent by his guardian, a doctor, to study medicine at the Ecole de Chirurgie in Paris. Around 1780 he entered the service of the Duke of Orléans as Surgeon. There he was able to pursue his interest in chemistry by carrying out research, particularly into crystallization; this bore fruit in a paper to the Royal Academy of Sciences in 1786, published in 1812 as a separate work entitled Crystallotechnie. At that time there was much concern that supplies of natural soda were becoming insufficient to meet the increasing demands of various industries, textile above all. In 1775 the Academy offered a prize of 2,400 livres for a means of manufacturing soda from sea salt. Several chemists studied the problem, but the prize was never awarded. However, in 1789 Leblanc reported in the Journal de physique for 1789 that he had devised a process, and he applied to his patron for support. The Duke had the process subjected to tests, and when these proved favourable he, with Leblanc and the referee, formed a company in February 1790 to exploit it. A patent was granted in 1791 and, with the manufacture of a vital substance at low cost based on a raw material, salt in unlimited supply, a bright prospect seemed to open out for Leblanc. The salt was treated with sulphuric acid to form salt-cake (sodium sulphate), which was then rotated with coal and limestone to form a substance from which the soda was extracted with water followed by evaporation. Hydrochloric acid was a valuable by-product, from which could be made calcium chloride, widely used in the textile and paper industries. The factory worked until 1793, but did not achieve regular production, and then disaster struck: Leblanc's principal patron, the Duke of Orléans, perished under the guillotine in the reign of terror; the factory was sequestered by the Revolutionary government and the agreement was revoked. Leblanc laboured in vain to secure adequate compensation. Eventually a grant was made towards the cost of restoring the factory, but it was quite inadequate, and in despair, Leblanc shot himself. However, his process proved to be one of the greatest inventions in the chemical industry, and was taken up in other countries and remained the leading process for the production of soda for a century. In 1855 his family tried again to vindicate his name and achieve compensation, this time with success.

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SUBJECT AREA: Chemical technology, Mining and extraction technology, Weapons and armour

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The son of a barber-surgeon who deserted his family to serve in the Swedish army, Nobel showed little interest in academic pursuits as a child and was sent to sea at the age of 16, but jumped ship in Egypt and was eventually employed as an architect by the pasha. Returning to Sweden, he won a scholarship to the Stockholm School of Architecture, where he studied from 1821 to 1825 and was awarded a number of prizes. His interest then leaned towards mechanical matters and he transferred to the Stockholm School of Engineering. Designs for linen-finishing machines won him a prize there, and he also patented a means of transforming rotary into reciprocating movement. He then entered the real-estate business and was successful until a fire in 1833 destroyed his house and everything he owned. By this time he had married and had two sons, with a third, Alfred (of Nobel Prize fame; see Alfred Nobel), on the way. Moving to more modest quarters on the outskirts of Stockholm, Immanuel resumed his inventions, concentrating largely on India rubber, which he applied to surgical instruments and military equipment, including a rubber knapsack.

It was talk of plans to construct a canal at Suez that first excited his interest in explosives. He saw them as a means of making mining more efficient and began to experiment in his backyard. However, this made him unpopular with his neighbours, and the city authorities ordered him to cease his investigations. By this time he was deeply in debt and in 1837 moved to Finland, leaving his family in Stockholm. He hoped to interest the Russians in land and sea mines and, after some four years, succeeded in obtaining financial backing from the Ministry of War, enabling him to set up a foundry and arms factory in St Petersburg and to bring his family over. By 1850 he was clear of debt in Sweden and had begun to acquire a high reputation as an inventor and industrialist. His invention of the horned contact mine was to be the basic pattern of the sea mine for almost the next 100 years, but he also created and manufactured a central-heating system based on hot-water pipes. His three sons, Ludwig, Robert and Alfred, had now joined him in his business, but even so the outbreak of war with Britain and France in the Crimea placed severe pressures on him. The Russians looked to him to convert their navy from sail to steam, even though he had no experience in naval propulsion, but the aftermath of the Crimean War brought financial ruin once more to Immanuel. Amongst the reforms brought in by Tsar Alexander II was a reliance on imports to equip the armed forces, so all domestic arms contracts were abruptly cancelled, including those being undertaken by Nobel. Unable to raise money from the banks, Immanuel was forced to declare himself bankrupt and leave Russia for his native Sweden. Nobel then reverted to his study of explosives, particularly of how to adapt the then highly unstable nitroglycerine, which had first been developed by Ascanio Sobrero in 1847, for blasting and mining. Nobel believed that this could be done by mixing it with gunpowder, but could not establish the right proportions. His son Alfred pursued the matter semi-independently and eventually evolved the principle of the primary charge (and through it created the blasting cap), having taken out a patent for a nitroglycerine product in his own name; the eventual result of this was called dynamite. Father and son eventually fell out over Alfred's independent line, but worse was to follow. In September 1864 Immanuel's youngest son, Oscar, then studying chemistry at Uppsala University, was killed in an explosion in Alfred's laboratory: Immanuel suffered a stroke, but this only temporarily incapacitated him, and he continued to put forward new ideas. These included making timber a more flexible material through gluing crossed veneers under pressure and bending waste timber under steam, a concept which eventually came to fruition in the form of plywood.

In 1868 Immanuel and Alfred were jointly awarded the prestigious Letterstedt Prize for their work on explosives, but Alfred never for-gave his father for retaining the medal without offering it to him.

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SUBJECT AREA: Metallurgy

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Wollaston qualified in medicine at Cambridge University but gave up his practice in 1800 to devote himself to chemistry and metallurgy, funded from the profits from making malleable platinum. In partnership with Smithson Tennant, a friend from his Cambridge days, he worked on the extraction of platinum by dissolving it in aqua regia. In 1802 he found that in addition to platinum the solution contained a new metal, which he named palladium. Two years later he identified another new metal, rhodium.

Wollaston developed a method of forming platinum by means of powder metallurgy and was the first to produce malleable and ductile platinum on a commercial scale. He produced platinum vessels for sulphuric acid manufacture and scientific apparatus such as crucibles. He devised an elegant method for forming fine platinum wire. He also applied his inventive talents to improving scientific apparatus, including the sextant and microscope and a reflecting goniometer for measuring crystal angles. In 1807 he was appointed Joint Secretary of the Royal Society with Sir Humphry Davy, which entailed a heavy workload and required them to referee all the papers submitted to the Society for publication.

Wollaston's output of platinum began to decline after 1822. Due to ill health he ceased business operations in 1828 and at last made public the details of his secret platinum fabrication process. It was fully described in the Bakerian Lecture he delivered to the Royal Society on 28 November 1828, shortly before his death.

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