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metal-to-metal+bonding

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  • Metal nitrosyl complex — Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transition metal.[1] Many kinds of nitrosyl complexes are known, which vary both in structure and coligand. Contents 1 Bonding and structure 1.1 Linear vs bent… …   Wikipedia

  • Metal sulfur dioxide complex — Metal sulfur dioxide complexes are complexes that contain sulfur dioxide, SO2, bonded to a transition metal.[1] Such compounds are common but are mainly of theoretical interest. Historically, the study of these compounds has provided insights… …   Wikipedia

  • Metal-organic framework — Metal Organic Frameworks are crystalline compounds consisting of metal ions or clusters coordinated to often rigid organic molecules to form one , two , or three dimensional structures that can be porous. In some cases, the pores are stable to… …   Wikipedia

  • Metal amides — are a class of coordination compounds composed of a metal center with amide ligands of the form NR2. Amide ligands have two electron pairs available for bonding. In principle, they can be terminal or bridging. In these two examples, the… …   Wikipedia

  • Metal K-edge — is the excitation of a 1s electron to valence bound states localized on the metal. The K edge can be divided into the pre edge region, which comprises the pre edge and rising edge transitions and the near edge region, which comprises the intense… …   Wikipedia

  • Metal nitrosyl — Metal nitrosyls are complexes that contain transition metals bonded to nitric oxide, NO. [Hayton, T. W.; Legzdins, P.; Sharp, W. B. Coordination and Organometallic Chemistry of Metal NO Complexes Chemical Reviews 2002, volume 102, pages 935 991;… …   Wikipedia

  • Metal acetylacetonates — are coordination complexes derived from the acetylacetonate anion and metal ions, usually transition metals. The ligand acetylacetonate is often abbreviated acac. Typically both oxygen atoms bind to the metal to form a six membered chelate ring.… …   Wikipedia

  • Metal carbon dioxide complex — Metal carbon dioxide complexes are coordination complexes that contain carbon dioxide ligands. Aside from the fundamental interest in the coordination chemistry of simple molecules, studies in this field are motivated by the possibility that… …   Wikipedia

  • Metal nitrido complex — Metal nitrido complexes are coordination compounds and metal clusters that contain an atom of nitrogen bound only to transition metals. These compounds are molecular, i.e. discrete in contrast to th polymeric, dense nitride materials that are… …   Wikipedia

  • Metal carbonyl — Iron pentacarbonyl An iron atom with five CO ligands Metal carbonyls are coordination complexes of transition metals with carbon monoxide ligands. These complexes may be homoleptic, that is containing only CO ligands, such as nickel carbonyl… …   Wikipedia

  • Metal–ligand multiple bond — In Chemistry, a metal–ligand multiple bond describes the interaction of certain ligands with a metal with a bond order greater than one.[1] Coordination complexes featuring multiply bonded ligands are of both scholarly and practical interest.… …   Wikipedia

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